Molecular Weight Distribution from the Normal Coordinate Theory of Viscoelasticity
- 1 September 1961
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 35 (3) , 946-950
- https://doi.org/10.1063/1.1701243
Abstract
The normal coordinate theory of viscoelasticity has been shown to provide a bridge between the measurable rheological properties of linear polymers and their molecular weight distribution functions, as well as their average molecular weights. Equations have been derived relating the molecular weight distribution function of a linear polymer to a sum of functions of a measurable rheological property such as stress relaxation or dynamic viscosity. Thus, a method for the simple and rapid determination of molecular weight distribution has been developed within the limitations of the normal coordinate theory.Keywords
This publication has 7 references indexed in Scilit:
- Molecular‐Weight Dependence of the Viscoelastic Properties of Whole PolymersThe Journal of Chemical Physics, 1961
- Existence of a sharply defined maximum relaxation time for monodisperse polystyreneJournal of Polymer Science, 1959
- Dependence of Intrinsic Viscosity of Dilute Solutions of Macromolecules on Velocity GradientThe Journal of Chemical Physics, 1956
- Dynamics of Polymer Molecules in Dilute Solution: Viscoelasticity, Flow Birefringence and Dielectric LossThe Journal of Chemical Physics, 1956
- The Viscoelastic Properties of PlasticsThe Journal of Chemical Physics, 1954
- A Theory of the Linear Viscoelastic Properties of Dilute Solutions of Coiling PolymersThe Journal of Chemical Physics, 1953
- Mechanical Properties of Substances of High Molecular Weight. IX. Non-Newtonian Flow and Stress Relaxation in Concentrated Polyisobutylene and Polystyrene SolutionsJournal of Applied Physics, 1951