Syntheses in the Isocamphane Series. XXXI1. 7-Oxacamphenilone, 7-Oxacamphene and 7-Oxacampheneilanic Acid
- 1 January 1988
- journal article
- research article
- Published by CLOCKSS Archive in HETEROCYCLES
- Vol. 27 (5) , 1217-1226
- https://doi.org/10.3987/com-87-4469
Abstract
The syntheses of the title compounds and their organoleptic properties are described. 7-Oxacamphenilone (2) has been obtained by two-fold methylation of 7-oxoanorbornan-2-one (1). The synthesis of 7-oxacamophene (5) has been accomplished by dehydration of 7-oxamethylcamphenilol (4). 7-Oxacamphenilanic acid (8) and some derivatives have been prepared starting with 5 by means of a hydroboration step and subsequent oxidation.Keywords
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