Some dihydro-cytidines and -isocytidines

Abstract
Syntheses of 5,6-dihydrocytidine (IV), 5,6-dihydroisocytidine (V), and the 2-thioanalogue (VII) of the former are described. U.v. spectroscopic data for (V) and its 2-N-methyl and 2,2-di-N-methyl derivatives (IX) and (X) in alcoholic solution reveal amino rather than imino tautomeric states. The n.m.r. spectra of the dihydrocytidines and their derivatives are reported.

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