Capillary phenomena. Part 5.—Equilibrium and stability of solid cones in fluid/fluid interfaces
- 1 January 1977
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases
- Vol. 73, 1882-1890
- https://doi.org/10.1039/f19777301882
Abstract
Conditions are given for the equilibrium paths followed by cones (axis vertical) in interfaces between two fluids, when raised and lowered by an applied force: using a tensiometer or a rigid (damped) device. Circumstances are described under which these conditions are stable. The instability and detachment of cones with contact angle θ < χ+ 90°, where χ is the half-angle at the apex of the cone generating triangle, at a maximum in the displacement of the cone apex gives a method of determining the fluid/fluid interfacial tension. Conditions under which cones can float unaided are also given. Comparison is made with the behaviour of other capillary systems.Keywords
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