Preparation and properties of bis(difluorophosphino)- and tris(difluoro-phosphino)-amine
- 1 January 1975
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 10,p. 889-894
- https://doi.org/10.1039/dt9750000889
Abstract
Bis(difluorophosphino)amine, (F2P)2NH, and tris(difluorophosphino)amine, (F2P)3N, have been prepared by the gas-phase reaction of ammonia, trimethylamine, and chlorodifluorophosphine. The compounds have been characterised by i.r., Raman, n.m.r., mass, and photoeiectron spectroscopy. The tertiary amine reacts with hydrides HX (X = Cl, Br, or I) and H2Y (Y = O, S, Se, or Te) to give the secondary amine and PF2X or YPF2H; OPF2H, SPF2H, and TePF2H decompose further.Keywords
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