Hydrido-complexes of osmium(II) and osmium(IV)
- 1 January 1973
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 9,p. 997-1004
- https://doi.org/10.1039/dt9730000997
Abstract
The preparations of [OsH4L3](L = tertiary phosphine or arsine) are described. Many neutral ligands L′(but not dinitrogen) will displace dihydrogen yielding complexes cis-[OsH2L3L′]. The hydrido-complexes are Lewis bases. They are also catalysts for olefin isomerisation and polymerization.Keywords
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