Kinetic Resolution of Racemic Allenes by Using Chiral (Salen)manganese(III) Complex as a Catalyst
- 1 May 1998
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 1998 (5) , 543-545
- https://doi.org/10.1055/s-1998-1719
Abstract
Enantiomer-differentiating oxidation of racemic 1,3-diarylallenes using optically active (salen)manganese(III) complex (1) as a catalyst, was found to proceed with high relative rate constants (up to 23), providing the enantiomerically enriched 1,3-diarylallenes.Keywords
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