Interconversion and degradation of acyl and enolato-ligands in triosmium clusters
- 1 January 1977
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 13,p. 472-473
- https://doi.org/10.1039/c39770000472
Abstract
The bridging acyl compounds [HOs3(COR)(CO)10](R = Ph, PhCH2, n-C5H11, n-C6H13, or Pri), derived from aldehydes, and the bridging enolato-compounds [HOs3(OCHCR2)(CO)10](R = H, Me, or Ph), derived from ketens, give decarbonylated products at 150 °C, some by interconversion of these two forms.Keywords
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