A short asymmetric synthesis of anthracycline antibiotics
- 1 January 1989
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 24,p. 1921-1922
- https://doi.org/10.1039/c39890001921
Abstract
Enantioselective dihydroxylation of (7) with osmium tetroxide with mediation by the chiral diamine (–)-(6) afforded (9) of 82% enantiomeric excess which was then successfully converted to (+)-4-demethoxydaunomycinone (5).Keywords
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