Crown thioether chemistry: bis(1,4,7-trithiacyclononane)rhenium(II), the first homoleptic thioether complex of rhenium

Abstract
FAB–MS, magnetic susceptibility, CV and X-ray diffraction establish [Re(9S3)2]2+(9S3 = 1,4,7-trithiacyclononane) as the first homoleptic thioether complex of Re, a compound of potential utility in cancer therapy.

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