Photocatalysis of metal clusters in cages: effective photoactivation of the water gas shift reaction catalysed on NaY zeolite-entrapped Pt12 and Pt9 carbonyl clusters
- 1 January 1992
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 13,p. 962-963
- https://doi.org/10.1039/c39920000962
Abstract
Pt carbonyl clusters [Pt3(CO)6]n,2–(n= 3,4) in NaY zeolite pores are catalytically active for the water gas shift reaction (CO + H2O) at low temperatures, and exhibited effective photocatalysis for this reaction with a marked enhancement (ca. 38 times higher at 293 K) under illumination from a Xe lamp compared with the dark reaction.Keywords
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