Ionic dissociation in pyridine–iodine solutions

Abstract
An electrochemical technique has been employed to study the ionization of the pyridine–iodine complex in pure pyridine and in 1,2-dichloroethane. A mechanism for the ionization in accord with the experimental data is proposed. The results indicate that, for wide ranges of iodine and pyridine concentration, one quarter of the I2 is dissociated into ionic species.

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