Regioselective alkylation of tungsten diazoalkane complexes via alkenyldiazenido complexes
- 1 January 1990
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 22,p. 1569-1571
- https://doi.org/10.1039/c39900001569
Abstract
Tungsten alkenyldiazenido complexes, which are obtained by the deprotonation of diazoalkane complexes trans-[WF(NNCRR′)(dpe)2][BF4](dpe = Ph2PCH2CH2PPh2) with lithium diisopropylamide (LDA) or NaN(SiMe3)2, undergo regioselective alkylation to give the C-alkylated diazoalkane complexes.Keywords
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