Improved Preparation of Bicyclo-Proptlidehe
- 1 June 1986
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 16 (7) , 837-845
- https://doi.org/10.1080/00397918608059666
Abstract
A reproducible synthesis of the title compound 6 in 10 - 20 g quantities is reported. The use of a polymeric base such as (diethylaminome-thyl)-polystyrene is exemplified in the transformation of a sensitive alcohol 4 into a labile chloride 5.Keywords
This publication has 8 references indexed in Scilit:
- Photooxidation of dispiro[2.0.2.4]deca-7,9-diene and its analogues: synthesis and properties of new nonenolizable cyclohex-2-ene-1,4-dionesTetrahedron, 1986
- Bonding properties of bicyclopropylidene: gas phase electron diffraction study and X-ray crystal structure analysisJournal of Molecular Structure, 1984
- Drei Variationen der [2 + 2]-Cycloaddition von BicyclopropylidenAngewandte Chemie, 1980
- Untersuchungen über kleine Ringsysteme, XXXV: Neue 1,1′‐Bicyclopropane und ein verbesserter Zugang zu 1,1′‐BicyclopropylidenEuropean Journal of Inorganic Chemistry, 1976
- Eliminierungen am Dreiring_Cyclopropyl-cyclopropen und Bicyclopropyliden aus 1-Chlor-bicyclopropylAngewandte Chemie, 1973
- [2 + 2] - und [2 + 4] -Cycloadditionen des BicyclopropylidensAngewandte Chemie, 1973
- Chemistry of cyclopropene preparation and reactivity of the cycloprop‐1‐enyl anion in liquid ammonia: (Preliminary communication)Recueil des Travaux Chimiques des Pays-Bas, 1971
- Synthesis of cyclopropanes by the reaction of olefins with dialkylzinc and methylene iodideTetrahedron, 1968