Regiospecific, stereospecific ring closure of alkenylperoxyl radicals generated by oxygenation of benzenethiol–triene mixtures
- 1 January 1980
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 11,p. 485-486
- https://doi.org/10.1039/c39800000485
Abstract
Oxygenation of mixtures of benzenethiol and octa-1,3,6-triene (1a) or 5-methylhepta-1,3,6-triene (1b) with free-radical initiation affords, after treatment of the initial products with triphenylphosphine, the 1,2-dioxolans (9a) and (9b), respectively, via mechanisms involving stereospecific and regiospecific ring closure of the alkenylperoxyl radicals (4a) and (4b).Keywords
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