Oxidation of A 4-Benzoyl-2-Azetidinone by Potassium Peroxomonosulfate
- 1 November 1988
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 18 (16) , 2129-2133
- https://doi.org/10.1080/00397918808068283
Abstract
KHSO5 oxidizes the ketone I to the corresponding benzoate II in satisfactory yield, under very mild conditions. No oxidation of the alcoholic group was detected.Keywords
This publication has 12 references indexed in Scilit:
- A novel synthesis of ()-4-acetoxy-3-[()-1-(-butyldimethylsilyloxy)ethyl]-2-azetidinone, the versatile key intermediate of carbapenem synthesis, from ()-ethyl lactateTetrahedron Letters, 1986
- A Synthesis of a Versatile Intermediate Leading to Thienamycin AnalogsBulletin of the Chemical Society of Japan, 1985
- A FACILE, STEREOCONTROLLED ENTRY TO KEY INTERMEDIATES FOR THIENAMYCIN SYNTHESIS FROM ETHYL (S)-3-HYDROXYBUTANOATEChemistry Letters, 1985
- Dioxiranes: synthesis and reactions of methyldioxiranesThe Journal of Organic Chemistry, 1985
- A SYNTHETIC APPROACH TO (+)-THIENAMYCIN FROM METHYL (R)-3-HYDROXYBUTANOATE. A NEW ENTRY TO (3R, 4R)-3-[(R)-1-HYDROXYETHYL]-4-ACETOXY-2-AZETIDINONEChemistry Letters, 1985
- A new synthetic strategy for the penems. Total synthesis of (5R,6S,8R)-6-(.alpha.-hydroxyethyl)-2-(hydroxymethyl)penem-3-carboxylic acidJournal of the American Chemical Society, 1985
- Metalloporphyrin-catalysed epoxidation of terminal aliphatic olefins with hypochlorite salts or potassium hydrogen persulphateJournal of the Chemical Society, Perkin Transactions 2, 1985
- Asymmetric epoxidation of unfunctionalized alkenes by dioxirane intermediates generated from potassium peroxomonosulphate and chiral ketonesJournal of the Chemical Society, Chemical Communications, 1984
- Stereocontrolled syntheses of chiral and racemic key intermediates to thienamycin from d-allo-threonine and trans-crotonic acidTetrahedron, 1983
- Stereocontrolled syntheses of chiral intermediates of thienamycin from threoninesTetrahedron Letters, 1981