Magnetic and electronic properties of HOPG/MoF6 graphite intercalation compounds: An ESR study
- 15 October 1985
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 83 (8) , 3859-3862
- https://doi.org/10.1063/1.449096
Abstract
The diamagnetic MoF6 molecule intercalates into graphite (HOPG) according to the reaction nC+MoF6 → C+xn(MoF−6)x (MoF6)1−x. Combination of ESR and magnetic susceptibility measurements indicate that the charge transfer is incomplete with x∼0.2. The system HOPG/MoF6 is unique in that ESR resonances due to both the 4d1 intercalant species (MoF−6) and conduction carriers can be detected. The ESR spectra of stage III exhibit an additional resonance which is probably associated with graphite interior layers.Keywords
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