Conductimetric studies in ketonic solvents. Part V. Quaternary ammonium salts in ethyl methyl ketone
- 1 January 1967
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 1093-1096
- https://doi.org/10.1039/j19670001093
Abstract
Conductances in ethyl methyl ketone at 25° are reported for a series of quaternary alkylammonium salts including the tetra-n-alkylammonium iodides and bromides from methyl up to n-octyl. Single-ion conductances have been evaluated by use of n-butyltri-isopentylammonium tetraphenylboride as the reference electrolyte. Hydrodynamic radii give no evidence of solvation of the cations while association parameters indicate anion penetration of the cations in association.Keywords
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