Equation of state and melting properties offrom measurements to 20 kbar
- 1 June 1980
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review B
- Vol. 21 (11) , 5137-5148
- https://doi.org/10.1103/physrevb.21.5137
Abstract
We measured simultaneously the pressure, volume, temperature, and ultrasonic longitudinal velocity in fluid from 75 to 300 K and 2 to 20 kbar. The data were fitted to a Benedict-type equation of state from which various thermodynamic quantities were calculated. From 75 to 97 K the measurements extended into the solid region, yielding values of the melting properties and new constants for the Simon melting equation. We used the Lindemann relation to determine a Debye temperature from which the ultrasonic transverse velocity of solid. was estimated. The melting entropy was analyzed to determine the contribution due to disordering of the atoms.
Keywords
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