Homoleptic Lanthanide Amides as Homogeneous Catalysts for the Tishchenko Reaction
- 19 June 1998
- journal article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 37 (11) , 1569-1571
- https://doi.org/10.1002/(sici)1521-3773(19980619)37:11<1569::aid-anie1569>3.0.co;2-c
Abstract
Known for about 25 years, the bis(trimethylsilyl)amides of Group 3 metals and lanthanides, M[N(SiMe3)2]3, are well suited as highly efficient catalysts for the dimerization of aldehydes [Tishchenko reaction, Eq. (1)].Keywords
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