Perturbation theory for multicomponent molecular fluids

Abstract
A Barker-Henderson like perturbation theory formulated for polyatomic fluids is employed to determine excess thermodynamic functions of argon + nitrogen and argon + oxygen mixtures. Molecular interactions are described by an ISM potential and the properties of the reference system are calculated from a modified version of Boublik's equation of state for hard convex bodies; the site-site correlation functions are evaluated from the RISM equation.

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