Synthesis of Some Analogs of the Methyl α-Glycoside of the Presumed Antigenic Determinant of the O-Specific Polysaccharide ofVibrio choleraeO:1, Serotype Ogawa

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Abstract
The following analogs of the title determinant, methyl 4,6-dideoxy-4-(3-deoxy-L-glycero-tetronamido)-2-O-methyl-α-D-mannopyranoside, have been prepared: methyl 3,4,6-trideoxy-4-(3-deoxy-L-glycero-tetronamido)-2-O-methyl-α-D-mannopyranoside, methyl 4,6-dideoxy-4-(4-hy droxybutyramido)-2-O-methyl-α-D-mannopyranoside, methyl 4,6-dideoxy-4-(3,4-dideoxy-L-glycero-tetronamido)-2-O-methyl-1-a-D-mannopyranoside, methyl 4,6-dideoxy-4-(3-deoxy-D-glycero-tetronamido)-2-O-methyl-α-D- mannopyranoside, methyl 4,6-dideoxy-4-(2-deoxy-L-glycero-tetronamido)-2-O-methyl-α-D- mannopyranoside, methyl 4-acetamido-4,6-dideoxy-2-O-methyl-α-D-mannopyranoside, methyl 4,6-dideoxy-4-(3-deoxy-L-glycero-tetronamido)-2-O-ethyl-α-D-mannopyranoside, and methyl 4,6-dideoxy-4-(3-deoxy-L-glycero-tetronamido)-2-O-propyl-α-D- mannopyranoside.

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