A DETERMINATION OF THE SURFACE FREE ENERGY OF SODIUM CHLORIDE

Abstract
The surface free energy for the interface between crystalline sodium chloride and a saturated alcoholic solution was determined from the solubility of sodium chloride in absolute ethyl alcohol as a function of the particle size of the salt. At 298°K. a value of 171 ergs/cm.2 was found. A general discussion of the validity of the Ostwald equation, which relates solubility and particle size, is presented.