111Cd and113Cd transferred hyperfine interactions in CsCdF3
- 14 October 1976
- journal article
- Published by IOP Publishing in Journal of Physics C: Solid State Physics
- Vol. 9 (19) , L529-L532
- https://doi.org/10.1088/0022-3719/9/19/003
Abstract
The ENDOR technique has been used to investigate the electron distribution in CsCdF3 crystals containing Mn2+, Ni2+ and Co2+. The bond structure is of the form M2+-F--Cd2+, where M stands for Mn, Ni or Co, and the measured isotropic 111Cd and 113Cd hyperfine interaction is taken to be proportional to the unpaired spin fraction, fsigma , in 2psigma orbitals on F-. The results suggest that for the Mn2+-F- bond fsigma =4.3%, which is much larger than estimates from neutron scattering data though in reasonable agreement with work by Rinneberg and Shirley (1973, 1976) who used a method involving perturbed angular correlation of gamma -rays from 111mCd.Keywords
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