Baeyer–Villiger oxidation of bicycloheptanone to cyclopentapyranone: a novel synthesis of iridomyrmecin, isoiridomyrmecin, and boschnialactone
- 1 January 1989
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 24,p. 1876-1878
- https://doi.org/10.1039/c39890001876
Abstract
Stereocontrolled syntheses of iridomyrmecin, isoiridomyrmecin, and boschnialactone are accomplished through a Baeyer–Villiger oxidation and either a cuprate coupling reaction or catalytic hydrogenation.Keywords
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