An efficient construction of 1,2-trans-.BETA.-glycosidic linkages via benzyl-protected glycopyranosyl P,P-diphenyl-N-(p-toluenesulfonyl)-phosphinimidates.
- 1 January 1990
- journal article
- Published by Pharmaceutical Society of Japan in CHEMICAL & PHARMACEUTICAL BULLETIN
- Vol. 38 (8) , 2323-2325
- https://doi.org/10.1248/cpb.38.2323
Abstract
An efficient 1, 2-trans-glycosidation reaction withon neighbouring group participation has been developed using benzyl-protected P, P-diphenyl-N-(p-toluensulfonyl)phosphinimidates as glycosyl donors in the presence of trimethylsilyl triflate or boron trifluoride etherate.Keywords
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