Kinetics of reactions of Schiff-base complexes of iron(II). Part IV. Reaction of tris-[α-(2-pyridyl)benzylideneaniline]iron(II) complexes with cyanide in aqueous alcohols

1 January 1971

journal article
research article
Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A

p. 44-48
https://doi.org/10.1039/j19710000044

Abstract

Kinetics of reaction of tris-[α-(2-pyridyl)benzylideneaniline]iron(II) complexes with cyanide in a range of aqueous alcohols indicate a bimolecular reaction mechanism. Second-order rate constants correlate with rate constants for aquation of the respective complexes, and with Grunwald–Winstein solvent Y values.

Keywords

KINETICS

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