Metall-Bor-Verbindungen, XII / Metal Boron Compounds, XII
Open Access
- 1 June 1971
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 26 (6) , 497-503
- https://doi.org/10.1515/znb-1971-0601
Abstract
Diphenylboryl stannanes [ (C6H5) 2B]4 - nSn(CH3) n (n = 0, 1, 2, 3) are produced from methyl chloro stannanes and (diphos)2Co[B(C6H5) 2] 2. However, no dibromoboryl stannanes (Br2B)4 - nSn(CH3)n could be isolated in a similar reaction using (diphos) 2Co(BBr2) 2 but they are stabilized by addition of diphos yielding the complexes (Br2B)4 - nSn(CH3)n · m diphos which contain B — P bonds.Keywords
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