Preorganization of tetrathiamacrocyclic ligands: implications from computed and experimentally determined structures

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Abstract
The tetrathiamacrocycles trans-6,13-dihydroxy-1,4,8,11-tetrathiacyclotetradecane (L1) and its benzo- (L2), syn- and anti-dibenzo-substituted derivatives (L3 and L3′, respectively) have been prepared by conventional methods, and a benzo-substituted-1,4,7,10-tetrathiacyclotridecane (L4) was obtained by substitution

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