A new and simple synthesis of tropones
- 1 January 1982
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 15,p. 847-848
- https://doi.org/10.1039/c39820000847
Abstract
3-and 4-Halogenocycloheptatrienones can be prepared from the Δ2- and Δ3-norcarenes (1), (2), and (3) by an allylic oxidation-dehydrohalogenation sequence; evidence for the intermediacy of the bicyclic enones (4)–(7) in the formation of the troponoid skeleton is presented.Keywords
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