NiCl2/CrCl2-Mediated Coupling Reaction of Ketones with Alkenyl(or Alkynyl, Aryl) Halides Accomplished in the Presence of a Bipyridyl-Type Ligand
- 31 December 1998
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 1998 (12) , 1311-1312
- https://doi.org/10.1055/s-1998-1984
Abstract
In this work, alkenyl halides (or triflates) and alkynyl (or aryl) halides are readily coupled with ketones in tetrahydrofuran in the presence of ligand 1, NiCl2 and CrCl2 at room temperature subsequently yielding the corresponding allylic alcohols, propargylic alcohols and benzylic alcohols.Keywords
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