Charge separation on the micelle surface as evidence for a multi-step hydrogen transfer mechanism in NADH model reduction
- 1 January 1982
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 11,p. 592-594
- https://doi.org/10.1039/c39820000592
Abstract
Reductive desulphonation of 2,4,6-trinitrobenzenesulphonate by N-dodecyl-1-benzyl-1,4-dihydronicotinamide bound to the sodium dodecyl sulphate micelle in D2O solution gave 1,3,5-trinitrobenzene which contained 4.6–5.1% of deuterium; the result indicates that the reaction proceeds through multi-step hydrogen transfer via a radical ion-pair intermediate and the micelle surface is capable of dissociating the radical ion pair.Keywords
This publication has 0 references indexed in Scilit: