Theoretical analysis of singlet–triplet energy splitting generated by charge-transfer interaction in electron donor–acceptor radical pair systems
- 8 July 2000
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 113 (2) , 465-468
- https://doi.org/10.1063/1.481823
Abstract
A theoretical analysis was performed for a prediction of the singlet–triplet energy splitting (J) of electron donor–acceptor radical pairs on the basis of the electron transferreactiontheory. It has been strongly indicated that charge-transfer interaction dominates the J in condensed phase photoinduced electron transfer systems.Keywords
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