Long-range spin-spin coupling in avenaciolide and related compounds

1 January 1965

journal article
research article
Published by CSIRO Publishing in Australian Journal of Chemistry

Vol. 18 (3) , 373-377
https://doi.org/10.1071/ch9650373

Abstract

The allylic system in avenaciolide (I) offers an example of exceptionally large allylic coupling constants with a reversed order of relative magnitude (Jcisoid 2.17 c/s; Jtransoid 2.56 c/s). Allylic coupling in related cyclic systems is discussed.

Keywords

C/S
SPIN SPIN
REVERSED ORDER
SPIN COUPLING
EXCEPTIONALLY LARGE
RELATIVE MAGNITUDE
AVENACIOLIDE
LARGE ALLYLIC