Determination of motional asymmetry of methyl rotators from 13C spin dynamics

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Abstract
Recent advances in the theory of dipolar relaxation in multispin systems are applied to studies of methyl rotators in isotropic fluids. A simple methodology is outlined which is very attractive for the investigation of anisotropic methyl group reorientation. It is demonstrated that this approach does not suffer from many of the inherent limitations of conventional applications of dipolar relaxation to such studies. Analogous extensions of the propounded method become temptingly obvious.

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