Etude Par Photolyse‐Eclair De La Photodegradation Sensibilisee De Spiro (Indoline‐Pyranes) Et De Spiro (Indoline‐Oxazines) Photochromiques
- 1 January 1992
- journal article
- european section
- Published by Wiley in Bulletin des Sociétés Chimiques Belges
- Vol. 101 (9) , 779-790
- https://doi.org/10.1002/bscb.19921010907
Abstract
The photodegradation and the “colorability” of photochromic spiro (indoline‐pyrans) and spiro (indoline‐oxazines) have been made by repeated flashes in solution open to the air. The photosensitization proceeds by triplet‐triplet energy transfert. For hight ratios photosensitizer/photochrome. (»100), the quenching by oxygen has no influence on the “colorability” which like that is optimized. The sensitized photodegradation is very important with a lifetime Vo about 3‐5 flashes whereas for the spirooxazines unsensitized Vo exceeds several thousands. This study enhances the hypothesis describing the photodegradation process of these molecules mainly via the triplet state.Keywords
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