A laboratory study of phosphorus mobilisation from commercial fertilisers

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Abstract
Phosphorus (P) exported from pastures following fertiliser application contributes to the nutrients and associated problems in the streams and rivers of south-eastern Australia. This laboratory study examined whether attributes of P fertilisers may affect P exports soon after their application to field soils; 3 commercial fertilisers [diammonium phosphate (DAP), single superphosphate (SSP), and sulfur-coated single superphosphate (CSSP)] were applied to 2 repacked soils (Arawata and Ellinbank) at 5 moisture contents. Soil type was the most important factor affecting water-extractable P (expressed as a percentage of the P added as fertiliser), accounting for 30% of the total variation. The majority of this variation is explained by the water-extractable P concentrations in the Arawata low moisture treatments. These treatments [7, 6, and 6% soil moisture when equilibrated at 99, 95, and 86.5% relative humidity (RH), respectively] contained water-extractable P concentrations c. 3 times higher than the high moisture (c. 20 and 25% soil moisture) or the Ellinbank treatments. This result probably reflects differences in soil properties including the extent of water repellency and P adsorption. Fertiliser type explained only 6.9% (P < 0.001) of the total variation in water-extractable P, partially as a result of the 86.5% RH (a low moisture) Arawata treatment. In this Arawata low moisture treatment, the mean extractable P was similar for both DAP and SSP, 13.1% [least significant interval (l.s.i.) 16.7–10.3] and 11.3% (l.s.i. 14.3–8.9), respectively, but for SSP, water-extractable P increased over time unlike any other treatment. Water-extractable P from DAP was approximately double that from SSP for the Ellinbank and high moisture treatments. The higher water-extractable P following DAP application is explained in terms of its chemical properties and reaction products. Sulfur coating the SSP granules (CSSP) increased water-extractable P, as did higher soil moisture. This study suggests that under conditions present in most pastures in south-eastern Australia and depending on soil hydrology, water-extractable P and P export from fertilisers may increase in the order DAP > CSSP > SSP if overland flow occurs soon after their application.

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