Glycosylations de Diols-4,6 en SerieGlucoetManno, Utilises Comme Accepteurs, Avec des DonneursN-Allyloxycarbonyles de la Glucosamine
- 1 July 1989
- journal article
- research article
- Published by Taylor & Francis in Journal of Carbohydrate Chemistry
- Vol. 8 (3) , 343-356
- https://doi.org/10.1080/07328308908048564
Abstract
Glycosylations were realized with N-allyloxycarbonyl derivatives of D-glucosamine on 4, 6-diols of the gluco and manno series. Depending on the donor used (either a glucosyl bromide or a β-acetate) and on the stoichiometry of reactants, a good regioselectivity could be observed towards the primary hydroxyl group. When the OH-6 is glycosylated or esterified the above donors are effective glycosylating agents towards the C-4 hydroxyl group.This publication has 14 references indexed in Scilit:
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