Generation of dimethylallene-carbene from 1,1-dichloro-2,2-dimethylcyclopropane
- 1 January 1969
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 20,p. 1206-1207
- https://doi.org/10.1039/c29690001206
Abstract
Treatment of 1,1-dichloro-2,2-dimethylcyclopropane with butoxide ion in hexamethylphosphoramide generates dimethylallene-carbene formed via an unsymmetrical intermediate and not via dimethylcyclopropyne, together with 3-methylbutenyne.Keywords
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