A study of C–35Cl coupling constants and 35Cl relaxation times through 13C relaxation in the rotating frame
- 1 March 1984
- journal article
- research article
- Published by Wiley in Magnetic Resonance in Chemistry
- Vol. 22 (3) , 164-166
- https://doi.org/10.1002/mrc.1270220306
Abstract
Values of one‐bond J(C35 Cl) and T1(35Cl) were determined for small chlorine‐containing molecules through 13C scalar relaxation in the rotating frame. A method is suggested for evaluating the contribution of scalar relaxation which eliminates experimental imperfections. The magnitude of J(C35Cl) seems to be influenced by the same factors as J(CF) values. The differences in 35Cl relaxation times are rationalized in terms of the molecular reorientation time.Keywords
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- Nuclear magnetic interactions and molecular motion in liquids by n.m.r. relaxation in the rotating frameJournal of Physics C: Solid State Physics, 1970