The Preparation and Structures of New Nido-Platinaheteroboranes
- 1 January 1980
- journal article
- research article
- Published by Taylor & Francis in Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry
- Vol. 10 (5) , 509-514
- https://doi.org/10.1080/00945718008071315
Abstract
Treatment of 4-XB8H12 (X=CH2, NH and S) hetero-boranes1–3 with Pt(PPh3)4 produced new ten-vertex platinaheteroboranes, 9,9-(PPh3)2-6,9-XPtB8H10 which are isoelectronic with nido-6-CB9H13. Their molecular structures were determined by single crystal X-ray studies. ESCA spectra were measured to estimate the influence of heteroborane ligands on central Pt atoms.Keywords
This publication has 3 references indexed in Scilit:
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- A General Theory for Cluster and Ring Compounds of the Main Group and Transition ElementsNature Physical Science, 1972
- Metalloboranes. IV. The B9H10S-, B9H11(L)2-, and B8H122- ligandsJournal of the American Chemical Society, 1970