Enantioselective total synthesis of (–)-xialenon A
- 24 September 2002
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- Vol. 34 (20) , 2436-2437
- https://doi.org/10.1039/b208485f
Abstract
The first total synthesis of (−)-xialenon A (1) via conjugate allylation of a 1,5-cyclooctadiene-derived bicyclo[3.3.0]octenone 3 and an α′-hydroxylation on the more hinderd face of enone 9 using hypervalent iodine chemistry, is described.Keywords
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