Dibenzo[a,d]cycloheptenyl dibenzophosphole palladium dichloride: Synthesis, X-ray-crystal structure and application in the Suzuki–Miyaura coupling
- 28 January 2005
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 12,p. 1592-1594
- https://doi.org/10.1039/b417716a
Abstract
A highly rigid dibenzo[a,d]cycloheptenyl dibenzophosphole with a pre-organized concave shaped binding site acts as an efficient ligand in the palladium catalyzed Suzuki–Miyaura coupling process between halogenoaromatics and phenylboronic acid.Keywords
This publication has 32 references indexed in Scilit:
- Pd-(MOP) Chemistry: Novel Bonding Modes and Interesting Charge DistributionOrganometallics, 2003
- A σ4, λ5-phosphinine palladium complex: a new type of phosphorus ligand and catalyst. Application to the Pd-catalyzed formation of arylboronic estersElectronic supplementary information (RSI) available: experimental procedures for a detailed preparation of complex 4 and cross-coupling experiments. See http://www.rsc.org/suppdata/cc/b2/b203550b/Chemical Communications, 2002
- Palladium Complexes of a Novel Family of P,N-Chelates, the 2-(2-Pyridyl)phospholes: Synthesis, Structural Characterization, and Catalytic Activity for Olefin/CO CopolymerizationOrganometallics, 2002
- A Highly Active Suzuki Catalyst for the Synthesis of Sterically Hindered Biaryls: Novel Ligand CoordinationJournal of the American Chemical Society, 2002
- Octaethyldiphosphaferrocene: An Efficient Ligand in the Palladium-Catalyzed Suzuki Cross-Coupling ReactionOrganometallics, 2000
- Hydroformylation of epoxides catalyzed by cobalt and hemilabile P–O ligandsChemical Communications, 2000
- Palladium(II) Complexes of 2-Dimethylamino-2‘- diphenylphosphino-1,1‘-binaphthyl (MAP) with Unique P,Cσ-Coordination and Their Catalytic Activity in Allylic Substitution, Hartwig−Buchwald Amination, and Suzuki CouplingJournal of the American Chemical Society, 1999
- Syntheses and Properties of Palladium Complexes Containing Phosphorus−Nitrogen−Phosphorus Ligands with a Tunable Hemilabile SiteOrganometallics, 1999
- Dibenzotropylidene phosphanes (TROPPs): synthesis and coinage metal complexesNew Journal of Chemistry, 1998
- MeO-Biphep and Binap Ligands as Six-Electron Donors to Ruthenium(II). X-ray and NMR Studies on Cp-, Pyrrole-, and Indole-Derived ComplexesOrganometallics, 1997