Configuration effects on electrode processes: optically active complexes of quadridentate Schiff bases. Part 2. Iron complexes
- 1 January 1977
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 23,p. 2327-2331
- https://doi.org/10.1039/dt9770002327
Abstract
Diastereoisomeric chelate complexes of the type [FeL(N3)](L = a quadridentate Schiff base derived from 1,2-di-substituted ethylenediamine and salicylaldehyde) show differences in several aspects of their electrode behaviour, including the parameters for heterogeneous electron transfer, adsorption on the electrode, and the equilibrium constant of axial-ligand dissociation coupled with the electrochemical reduction.Keywords
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