A synthesis of allylsilanes in which the silyl group is at the more-substituted end of the allyl group
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- p. 1809-1813
- https://doi.org/10.1039/p19840001809
Abstract
The allylsilanes (8), (11), (18)–(20), and (26), have been made by a three-step sequence from αβ-unsaturated esters. The steps are conjugate addition of the phenyldimethylsilyl group, lithium aluminium hydride reduction, and selenium-mediated dehydration. The route is versatile and leads regiospecifically to allylsilanes, in which the silyl group is at the more-substituted end of the allyl group.Keywords
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