Bistrifluoromethylamino-derivatives of phosphorus(V)

Abstract
Reaction of N-chlorobistrifluoromethylamine with phosphorus trifluoride and difluoromonochloride yields the compounds (CF3)2NPF3Cl and (CF3)2NPF2Cl2. Hydrolysis of the latter yields (CF3)2NPF2O. The 19F n.m.r. spectra are recorded and discussed.

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