Electrochemical studies of Group 3 alkyl derivatives. Part 1. Synthesis of trimethylgallium adducts
- 1 January 1983
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 6,p. 1047-1049
- https://doi.org/10.1039/dt9830001047
Abstract
Electrolysis of dimethylmagnesium in tetrahydrofuran (thf) with a gallium anode yields the adduct GaMe3·thf directly; the trialkylamine and trialkylphosphine adducts GaMe3·L (L = NEt3, PMe3, or PEt3) are obtained by direct addition of an excess of L to GaMe3·thf. Free GaMe3 is obtained by reaction of Mel with a Mg–Ga alloy in an ether solvent.Keywords
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