Preparation and Reactions of Functionalized Arylmagnesium Reagents
- 1 January 2002
- journal article
- psp
- Published by Georg Thieme Verlag KG in Synthesis
- Vol. 2002 (04) , 565-569
- https://doi.org/10.1055/s-2002-20955
Abstract
Functionalized magnesium reagents have been prepared via an iodine-magnesium exchange. These reagents can be either trapped directly with aldehydes or transmetallated to copper or zinc to participate in cross-coupling reactions. The iodine-magnesium exchange, represent a unique method for the preparation of aryl and heteroaryl magnesium reagents.Keywords
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