Theory of High Polymer Solutions (The Dumbbell Model)
- 1 April 1951
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 19 (4) , 397-403
- https://doi.org/10.1063/1.1748236
Abstract
Following the theories of McMillan, Mayer, and Zimm, and extending the previous theories of the author, the second virial coefficient A2 for high polymer solutions of the dumbbell model is calculated. The results are rigorous within the approximation of rigid‐body potential. A2 varies smoothly with l/R, where R is the radius of spheres of the dumbbell and l is their separation. Based on the present results, comparisons between the gas and the lattice theories are made.Keywords
This publication has 22 references indexed in Scilit:
- Statistical Mechanics of Dilute Polymer Solutions. IIThe Journal of Chemical Physics, 1950
- Light Scattering Investigation of the Structure of PolystyreneThe Journal of Chemical Physics, 1950
- The Intrinsic Viscosity, Translational and Rotatory Diffusion Constants of Rod-Like Macromolecules in SolutionThe Journal of Chemical Physics, 1950
- Size and Shape of Macromolecules in Solution.Industrial & Engineering Chemistry, 1946
- Thermodynamics of Dilute Solutions of High PolymersThe Journal of Chemical Physics, 1945
- THERMODYNAMIC PROPERTIES OF SOLUTIONS OF LONG‐CHAIN COMPOUNDSAnnals of the New York Academy of Sciences, 1942
- The interaction between rubber and liquids. 1. A thermodynamical study of the system rubber-benzeneTransactions of the Faraday Society, 1942
- Some Properties of Solutions of Long-chain Compounds.The Journal of Physical Chemistry, 1942
- The number of configurations in an assembly and cooperative phenomenaMathematical Proceedings of the Cambridge Philosophical Society, 1939
- Hydrierungs- und Oxydationsprodukte der Carotine als Vorstufen des A-Vitamins.Hoppe-Seyler´s Zeitschrift Für Physiologische Chemie, 1932