Starlike substituted hexaarylbenzenes: synthesis and mesomorphic properties
- 24 April 2001
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of Materials Chemistry
- Vol. 11 (6) , 1634-1641
- https://doi.org/10.1039/b101163o
Abstract
A series of hexaarylbenzenes (1–6) with a variety of different aryl arms (i.e. phenyl, biphenylyl, mono-, bi-, and terthienylyl) around a benzene core, decorated with flexible dodecyl chains on the terminal positions, were synthesized. Their mesomorphic behaviors were studied by differential scanning calorimetry (DSC), polarizing optical microscopy (POM) and X-ray diffraction (XD) techniques. Compounds 1–3, which have a hexaphenylbenzene core, form columnar mesophases. In particular 3, in which the core is composed of hexaphenylbenzene surrounded by thiophene rings, shows a stable columnar mesophase (d-Dh) over a large temperature range compared to its phenyl analogs, hexakis(4-dodecylphenyl-4-yl)benzene (1) and hexakis(4′-dodecylbiphenylyl)benzene (2). Compounds 4–6, hexa(oligo-α-thienylyl)benzenes, tend to form less ordered mesophases after annealing for a longer time. Compounds 4 and 5 form discotic nematic mesophases (Nd) at temperatures well below the decomposition temperature.Keywords
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